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Platinum(IV) chloride : ウィキペディア英語版 | Platinum(IV) chloride
Platinum(IV) chloride is the inorganic compound of platinum and chlorine with the empirical formula PtCl4. This brown solid features platinum in the 4+ oxidation state. ==Structure== Typical of Pt(IV), the metal centers adopt an octahedral coordination geometry, . This geometry is achieved by forming a polymer wherein half of the chloride ligands bridge between the platinum centers. Because of its polymeric structure, PtCl4 dissolves only upon breaking the chloride bridging ligands. Thus, addition of HCl give H2PtCl6. Lewis base adducts of Pt(IV) of the type cis-PtCl4L2 are known, but most are prepared by oxidation of the Pt(II) derivatives.
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